Webi report headers and footers cannot be exported to Excel. SAP offers the following workarounds,
Workaround 1:
- Place header and footer cells inside report page.
- If you have reports with many pages, right-click each cell and select Format Cell...
- Click Layout > Vertical > Repeat on every page.

Workaround 2:
- Save the Webi document as Excel.
- Open the saved Excel file and place the table headers in the page header of Excel and it will automatically get displayed on each page.